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化学进展 2024, Vol. 36 Issue (3): 367-375 DOI: 10.7536/PC230718 前一篇   后一篇

• 综述 •

MOFs在催化有机分子转化中的应用

李希臣1,2, 李政1,2, 彭灿1,2, 钱陈1,2, 韩雨霏1,2, 张涛1,2,*()   

  1. 1 南京医科大学药学院核药学系 南京 211166
    2 南京医科大学核医药临床转化中心 南京 210029
  • 收稿日期:2023-07-18 修回日期:2023-09-29 出版日期:2024-03-24 发布日期:2024-02-26
  • 作者简介:

    张涛 理学博士，2017年于南京大学获得博士学位。之后在美国北卡罗莱纳大学作为博士后从事生物医学工程研究。2021年3月起作为高层次人才引进到南京医科大学开展独立科学研究工作，主要从事临床重大疾病的化学生物学基础及分子影像学指导下的精准诊疗研究。

  • 基金资助:
    国家自然科学基金项目(12275135); 江苏省高校自然科学研究项目(21KJB350015); 南京医科大学引进人才科研启动基金(NMUR20210003); 南京医科大学内涵建设重点项目和南京医科大学科技发展基金(NMUB20210014); 江苏省高校自然科学研究项目(22KJB350008)
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Application of MOFs in Catalytic Conversion of Organic Molecules

Xichen Li1,2, Zheng Li1,2, Can Peng1,2, Chen Qian1,2, Yufei Han1,2, Tao Zhang1,2()   

  1. 1 Department of Radiopharmaceuticals, School of Pharmacy, Nanjing Medical University, Nanjing 211166, China
    2 Nuclear Medicine Clinical Transformation Center, Nanjing Medical University, Nanjing 210029, China
  • Received:2023-07-18 Revised:2023-09-29 Online:2024-03-24 Published:2024-02-26
  • Contact: * e-mail: zhangtaocjh@njmu.edu.cn
  • Supported by:
    National Natural Science Foundation of China(12275135); Jiangsu Province University Natural Science Research Project(21KJB350015); Nanjing Medical University Talent Introduction Research Start-up Fund(NMUR20210003); Key Project of Connotation Construction of Nanjing Medical University and Science and Technology Development Fund of Nanjing Medical University(NMUB20210014); Jiangsu Province University Natural Science Research Project(22KJB350008)

金属有机框架化合物（MOF），又称多孔性配位聚合物，是有机配体与金属离子自组装而成的一类新型有机-无机杂化多孔材料，是纳米材料的重要组成部分。与其他多孔材料相比，MOFs具有较大的比表面积、高的孔隙率以及结构和性质可调等特性，使其在非均相催化领域具有良好的应用前景。本文首先对MOFs催化的背景进行简述，然后对近年来报道的MOFs用于有机分子催化转化反应的进展进行了综述及展望，以期为MOFs催化有机反应的设计和开发提供参考。

关键词： 金属有机框架材料, 非均相催化, 界面金属有机化学, 有机分子, 高附加值化学品

Metal-organic framework compounds (MOF), also known as porous coordination polymers, are a new type of organic-inorganic hybrid porous materials which are self-assembled from organic ligands and metal ions, and are an important part of nanomaterials. Compared to other porous materials, MOFs have a large surface area, high porosity and adjustable structure and properties, making them have a good application prospect in heterogeneous catalysis. In this paper, the background of MOFs catalysis is briefly reviewed, followed by a review and prospect of the recent progress of MOFs in catalytic conversion reactions of organic molecules, in order to provide a reference for the design and development of organic reactions catalyzed by MOFs.

Contents

1 Introduction

2 Knoevenagel Condensation catalyzed by MOFs

3 Suzuki-Miyaura Reaction catalyzed by MOFs

4 Mizoroki-Heck Reaction catalyzed by MOFs

5 Aldol Condensation catalyzed by MOFs

6 A3-Coupling Reaction catalyzed by MOFs

7 Cycloaddition of CO2 catalyzed by MOFs

8 Oxidation and reduction of unsaturated hydrocarbons catalyzed by MOFs

9 Conclusion and outlook

Key words: metal-organic framework, heterogeneous catalysis, interfacial organometallic chemistry, organic molecules, high value-added chemicals
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图1 Knoevenagel缩合反应示意图
Fig. 1 Diagram of Knoevenagel condensation reaction
图2 UiO-66及其修饰改造示意图[13]
Fig. 2 Diagram of UiO-66 and its modifications[13]
图3 Suzuki-Miyaura反应示意图
Fig. 3 Diagram of Suzuki-Miyaura reaction
图4 UiO-66(L3)示意图[21]
Fig. 4 Diagram of UiO-66 (L3) [21]
图5 Mizoroki-Heck反应示意图
Fig. 5 Diagram of Mizoroki-Heck reaction
图6 Pd@Co3O4示意图[31]
Fig. 6 Diagram of Pd@Co3O4 [31]
图7 Aldol缩合反应示意图
Fig. 7 Diagram of Aldol condensation reaction
图8 A3-Coupling反应示意图
Fig. 8 Diagram of A3-Coupling reaction
图9 Au/MOF-199示意图[44]
Fig. 9 Diagram of Au/MOF-199[44]
图10 二氧化碳与环氧化合物成环反应示意图
Fig. 10 Diagram of the ring-forming reaction of carbon dioxide and epoxy compounds
图11 ZnO@NPC-Ox-700示意图[51]
Fig. 11 Diagram of ZnO@NPC-Ox-700[51]
图12 不饱和烃的氧化示意图
Fig. 12 Diagram of oxidation of unsaturated hydrocarbons
图13 Zn1Co1-ZIF示意图[55]
Fig. 13 Diagram of Zn1Co1-ZIF[55]
图14 不饱和烃的还原示意图
Fig. 14 Diagram of the reduction of unsaturated hydrocarbons
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摘要

MOFs在催化有机分子转化中的应用